Question 3.7:
Why does the conductivity of a solution decrease with dilution?
Answer:
The conductivity of a solution is the conductance of ions present in a unit volume of the solution. The number of ions (responsible for carrying current) decreases when the solution is diluted. As a result, the conductivity of a solution decreases with dilution.
Question 3.8:
Suggest a way to determine the value of water.
Answer:
Applying Kohlrausch’s law of independent migration of ions, the value of water can be determined as follows:
Hence, by knowing the values of HCl, NaOH, and NaCl, the value of water can be determined.
Question 3.9:
The molar conductivity of 0.025 mol L−1 methanoic acid is
46.1 S cm2 mol−1.
Calculate its degree of dissociation and dissociation constant. Given λ °(H+)
= 349.6 S cm2 mol−1 and λ °(HCOO−) = 54.6 S cm2 mol
Answer:
C = 0.025 mol L−1
Now, degree of dissociation:
Thus, dissociation constant: