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Page No 111: - Chapter 4 Chemical Kinetics Intext Solutions class 12 ncert solutions Chemistry - SaraNextGen [2024]


Question 4.5:

A first order reaction has a rate constant 1.15 10−3 s−1. How long will 5 g of this reactant take to reduce to 3 g?

Answer:

From the Question, we can write down the following information:

Initial amount = 5 g

Final concentration = 3 g

Rate constant = 1.15 10−3 s−1

We know that for a 1st order reaction,

https://img-nm.mnimgs.com/img/study_content/curr/1/12/17/263/6321/NCERT(INTEXT)_13-11-08_Utpal_12_Chemistry_4_9_html_m634877af.gif

= 444.38 s

= 444 s (approx)

Question 4.6:

Time required to decompose SO2Cl2 to half of its initial amount is 60 minutes. If the decomposition is a first order reaction, calculate the rate constant of the reaction.

Answer:

We know that for a 1st order reaction,

https://img-nm.mnimgs.com/img/study_content/curr/1/12/17/263/6322/NCERT(INTEXT)_13-11-08_Utpal_12_Chemistry_4_9_html_470b8c21.gif

It is given that t1/2 = 60 min

https://img-nm.mnimgs.com/img/study_content/curr/1/12/17/263/6322/NCERT(INTEXT)_13-11-08_Utpal_12_Chemistry_4_9_html_m2301ba1b.gif

Also Read : Page-No-116:-Chapter-4-Chemical-Kinetics-Intext-Solutions-class-12-ncert-solutions-Chemistry

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