SaraNextGen.Com

From amongst the following alcohols the one that would react fastest with conc. HCI and anhydrous is

1)

2-butanol

2)

2-methyl propan-2-ol

3)

2-methylpropanol

4)

1 butanol



Question ID - 100482 | SaraNextGen Top Answer

From amongst the following alcohols the one that would react fastest with conc. HCI and anhydrous is

1)

2-butanol

2)

2-methyl propan-2-ol

3)

2-methylpropanol

4)

1 butanol

1 Answer
127 votes
Answer Key / Explanation : (2) -

The reaction of alcohol with conc. HCl and anhydrous following 1 pathway, so greater the stability of carbocation formed, faster is the reaction.

2-methyl propan-2-ol gives 3  carbocation.

Hence, it reacts rapidly with conc. HCl and anhydrous (Lucas reagent).

127 votes


127