Which of the following reactions is/are correct? |
|
a) |
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b) |
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c) |
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d) |
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Which of the following reactions is/are correct? |
|
a) |
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b) |
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c) |
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d) |
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(a,b,d)
a. It is an example of Kolbe''s reaction
So both the products are correct
b. ( + HCl) selectively reduces
group
to (
(EDG) group, but (
) selectively reduces (
) group
to (
(EDG) group. So both the products are correct
c. Due to (+I) effect of three groups; the benzene the ring is activated and is unstable. So, the oxidation of benzene ring takes place, while due to the absence of benzylic H atom in t-butyl group, the oxidation of side chain does not take place. So the products (II) and (III) are correct, but product (I) is wrong. So the answer (c) is wrong
d. In acidic medium the (
) group is reduced to (
) group. So product (I) is correct. In neutral medium
or
group is reduced to (NHOH) group. So product (II) is correct
In basic medium with (
) group is converted to azoxy group, so product (III) is correct. Hence, the answers are (a), (b), and (d)