Compound exists in various structures as shown:
Which statement(s) is/are correct?
a) |
Compounds I and II give iodoform test.Compound I gives white turbidity on heating with Lucas reagent, while compound II reduces Tollens reagent |
b) |
Compound III gives silver mirror with |
c) |
Compound IV on acid hydrolysis gives |
d) |
Compound V on heating is decarboxylated to propane |
Compound exists in various structures as shown:
Which statement(s) is/are correct?
a) |
Compounds I and II give iodoform test.Compound I gives white turbidity on heating with Lucas reagent, while compound II reduces Tollens reagent |
b) |
Compound III gives silver mirror with |
c) |
Compound IV on acid hydrolysis gives |
d) |
Compound V on heating is decarboxylated to propane |
(a,b)
a. Compound (I) contains group and hence gives iodoform test. It also contains
alcoholic group and hence gives white turbidity on heating with Lucas reagent (anhydrous
: conc.
= 1:1). Compound (II) reduces Tollens reagent, although it does not contain (
) group but T.R. test is also given by
-hydroxy ketones
So the statement (a) is correct
b. Compound (III) is an aldehyde, so it gives positive T.R. test but it does not give haloform reaction with or (
+
), since it does not contain (
) group. So the statement (b) is also correct
But the answer given is . So statement (c) is wrong
d. Compound (V) on heating cannot decarboxylate, but with soda lime it can decarboxylate to give propane. Only acids containing -keto groups can easily undergo decarboxylation on heating
So the statement (d) is wrong
Hence, the answers are (a) and (b)