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The specific heats, cp and cv of a gas of diatomic molecules, A, are given (in units of j mol−1 ) by 29 and 22, respectively.  Another gas of diatomic molecules, B, has the corresponding values 30 and 21.  If they are treated as ideal gases, then:

(a) A is rigid but B has a vibrational mode.

(b) A has a vibrational mode but has none.

(c)  Both A and B have a vibrational mode each.

(d) A has a vibrational mode and B has two.    



Question ID - 51267 | SaraNextGen Top Answer

The specific heats, cp and cv of a gas of diatomic molecules, A, are given (in units of j mol−1 ) by 29 and 22, respectively.  Another gas of diatomic molecules, B, has the corresponding values 30 and 21.  If they are treated as ideal gases, then:

(a) A is rigid but B has a vibrational mode.

(b) A has a vibrational mode but has none.

(c)  Both A and B have a vibrational mode each.

(d) A has a vibrational mode and B has two.    

1 Answer
127 votes
Answer Key / Explanation : (b) -

For (A)CP=29, CV=22

For(B)CP=30 CV=22

∴     = = =1.31

When A has vibrational degree of freedom, then = =1.29.

= = =1.42

B has no vibrational degree of freedom

127 votes


127