At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behavior. Their equation of state is given as P= at T Here, b is the Vander Waal’s constant. Which gas will exhibit steepest increase in the plot of Z (compression factor) vs P? |
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(a) |
Kr |
(b) |
Ar |
(c) |
Xe |
(d) |
Ne |
At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behavior. Their equation of state is given as P= at T Here, b is the Vander Waal’s constant. Which gas will exhibit steepest increase in the plot of Z (compression factor) vs P? |
|||
(a) |
Kr |
(b) |
Ar |
(c) |
Xe |
(d) |
Ne |
P=
⇒PVm−Pb=RT
⇒ =1+
⇒Z=1+
Slope of Z vs curve (straight line) =
∴ Higher the value of b, more steep will be the curve and b size of gas molecules