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At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behavior.  Their equation of state is given as P=  at T

Here, b is the Vander Waal’s constant.  Which gas will exhibit steepest increase in the plot of Z (compression factor) vs P?

(a)

Kr

(b)

Ar

(c)

Xe

(d)

Ne



Question ID - 52658 | SaraNextGen Top Answer

At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behavior.  Their equation of state is given as P=  at T

Here, b is the Vander Waal’s constant.  Which gas will exhibit steepest increase in the plot of Z (compression factor) vs P?

(a)

Kr

(b)

Ar

(c)

Xe

(d)

Ne

1 Answer
127 votes
Answer Key / Explanation : (c) -

P=

⇒PVm−Pb=RT

=1+

⇒Z=1+

Slope of Z vs curve (straight line) =

∴   Higher the value of b, more steep will be the curve and b  size of gas molecules

127 votes


127