The molar solubility of Cd(OH)2 is 1.84 × 10−5 M in water. The expected solubility of Cd(OH)2 in a buffer solution of pH = 12 is:
a) |
1.84 × 10−9 M |
b) |
6.23 × 10−11 M |
c) |
10−9 M |
d) |
2.4910−10 M |
The molar solubility of Cd(OH)2 is 1.84 × 10−5 M in water. The expected solubility of Cd(OH)2 in a buffer solution of pH = 12 is:
a) |
1.84 × 10−9 M |
b) |
6.23 × 10−11 M |
c) |
10−9 M |
d) |
2.4910−10 M |
Cd(OH)2
At equilibrium, Ksp = S(2S)2
= 4S3
⇒ Ksp = 4 × (1.84 × 10−5)3
Solubility in buffer solution having pH = 12
[OH−] = 10−2
Cd(OH)2
Ksp = 4(1.84 10−5)3 = (10−2)2
⇒ = = 2.4910−10 M