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A keto ester  with molecular formula  on treatment with  does not give iodoform but on boiling with dilute KOH gives a compound  with molecular formula  which upon acidification followed by heating undergoes decarboxylation to give acetone. The keto ester  is

a)

b)

c)

d)



Question ID - 57565 | SaraNextGen Top Answer

A keto ester  with molecular formula  on treatment with  does not give iodoform but on boiling with dilute KOH gives a compound  with molecular formula  which upon acidification followed by heating undergoes decarboxylation to give acetone. The keto ester  is

a)

b)

c)

d)

1 Answer
127 votes
Answer Key / Explanation : (b) -

(b)

The keto-ester  does not give haloform reaction inspite of the presence of  group in it. The reason is the presence of active methylene group ), which prevents the conversion of

127 votes


127